The 37-year-old actress sparkled in a bronze Giorgio Armani Prive gown with rows of amber sequins and beaded detail at the waist, while husband Abhishek Bachchan stuck to a traditional black tuxedo.
The actress teamed the shimmery gown with a Jimmy Choo clutch, vintage jewellery and smoky eyes.
Like Abhishek, musician A R Rahman who walked the red carpet with wife Saira, too wore a tuxedo while his partner chose a flamboyant fusion ensemble consisting of a golden sherwani and cigarette pants.
Like Saira and Ash, the shimmer trend was followed by Gwnyeth Paltrow, who wore a gold Calvin Klein number and Halle Berry who stole the show in a nude sparkling number by Marchesa.
Hilary Swank's glistening silver Gucci column gave way to a romantic ostrich feather skirt, while the sparkling bodice of Mandy Moore's romantic Monique L'Hullier dress appeared to have been sprayed on.
Shimmering nude was also an age-appropriate choice for 14-year-old Hailee Steinfeld, nominated for her role in True Grit, who won a Fifties-style dress by Marchesa.
While Celine Dion, wore a full-sleeved silver column dress, Amy Adams added a pop of colour to the red carpet with a sequined navy gown by L'Wren Scott, which she teamed with green accessories.
Other than the sparkle, another major trend was the resurgence of the red carpet favourite, voluminous red gowns.
The bustled creations worn by Anne Hathaway, Jennifer Hudson, and Sandra Bullock, were in the same traffic-stopping hue of red. Penelope Cruz too showed off her post-pregnancy bod with a sequined red gown by L'Wren Scott.
And while black remained a popular choice, with famously eccentric British star Helena Bonham Carter opting for it, there were some surprises from Cate Blanchett who wore an lavender Givenchy Haute Couture gown with yellow embellishment, and an unusual purple-burgundy hue seen on both Natalie Portman, in Rodarte, and Scarlett Johansson in Dolce and Gabbana.
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